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A novel complex Tp(Me,Ph)Fe(SCH2CH2NH2) has been synthesized as a speculative model for ADO. Indeed its reaction with O2 led to the dioxygenation of the S atom and thus to hypotaurine. This finding may allow us to draw conclusions on the constitution of the ADO active site, whose structure is still unknown.

Dioxygenation of cysteamine to hypotaurine at a tris(pyrazolyl)borate iron(ii) unit – cysteamine dioxygenase mimicking?