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An original mechanistic study of the reaction of [(L)Fe II ] 2+  (L = TPEN) with dioxygen has been carried out by cyclic voltammetry. Electrochemical data of intermediates [(L)Fe IV (O)] 2+ , [(L)Fe III (OOH)] 2+  and [(L)Fe III (OO)] +  are reported. Reaction mechanism between this Fe II  complex and O 2  under reductive conditions is determined.

chemical science

Electrochemical study of a nonheme Fe(<scp>ii</scp>) complex in the presence of dioxygen. Insights into the reductive activation of O<sub>2</sub> at Fe(<scp>ii</scp>) centers

Electrochemical study of a nonheme Fe(ii) complex in the presence of dioxygen. Insights into the reductive activation of O2 at Fe(ii) centers

Electrochemical study of a nonheme Fe(ii) complex in the presence of dioxygen. Insights into the reductive activation of O₂ at Fe(ii) centers