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Ti 7 -containing [Ti 6 (TiO 6 )(AsW 9 O 33 ) 4 ] 20−  ( 1 ) comprises a central, octahedrally coordinated Ti 4+  ion bridged to six square-pyramidally coordinated Ti 4+  ions, and this titanium-oxo core is surrounded by four {AsW 9 O 33 } capping units, resulting in an overall tetrahedral assembly.

dalton transactions

Ti7-containing, tetrahedral 36-tungsto-4-arsenate(<scp>iii</scp>) [Ti6(TiO6)(AsW9O33)4]20−

Ti7-containing, tetrahedral 36-tungsto-4-arsenate(iii) [Ti6(TiO6)(AsW9O33)4]20−

Ti₇-containing, tetrahedral 36-tungsto-4-arsenate(iii) [Ti₆(TiO₆)(AsW₉O₃₃)₄]²⁰⁻