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Electron-poor {Ru(NO) 2 } 8 -type dinitrosyls exhibit an Ru II (NO + )(NO − ) moiety, electron-rich entities show an Ru 0 (NO + ) 2  situation, borderline compounds show both forms as photo-excitable species.

NO-binding in {Ru(NO)2}8-type [Ru(NO)2(PR3)2X]BF4 compounds

NO-binding in {Ru(NO)₂}⁸-type [Ru(NO)₂(PR₃)₂X]BF₄ compounds