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Li 17 Ge 4 was established as the lithium-richest and Li 4.10 Ge as a high-temperature phase in the revised Li-rich section of the Li–Ge phase diagram (&gt;79 at% Li).

dalton transactions

Structural and thermodynamic similarities of phases in the Li–Tt (Tt = Si, Ge) systems: redetermination of the lithium-rich side of the Li–Ge phase diagram and crystal structures of Li17Si4.0−xGexforx= 2.3, 3.1, 3.5, and 4 as well as Li4.1Ge