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Photodeposition of Pt on the Sc-doped La5Ti2CuS5O7 (Sc-LTC) photocathode, a visible-light-responsive semiconducting oxysulfide, is accomplished in a solution containing H2PtCl6 and K2C2O4. Pt particles are selectively deposited on the top surface of rod-like Sc-LTC particles as a result of one-dimensional transfer of photogenerated electrons.

chemical communications

Site-selective photodeposition of Pt on a particulate Sc-La5Ti2CuS5O7 photocathode: evidence for one-dimensional charge transfer