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Reaction of [(η 6 -C 6 Me 6 )Ru(Ph)(PMe 3 )] +  with internal alkynes gave rise to the 1,4-Ru migration to form the  o -vinylaryl complex, providing the first example of 1,4-metal migration of a group 8 metal center; in one case further isomerization to an η 3 -allyl complex was observed.

Remote rearrangement of the metal center in a (η6-C6Me6)Ru(ii) complex

Remote rearrangement of the metal center in a (η⁶-C₆Me₆)Ru(ii) complex