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A series of two conjugates with La2@C80 and subphthalocyanine (SubPc) have been prepared and characterized by means of cyclic voltammetry, absorption, fluorescence, and femtosecond resolved transient absorption spectroscopy. The strong electron-donating character of La2@C80 is essential to power an intramolecular electron-transfer in the La2@C80-SubPc conjugates upon photoexcitation.

chemical communications

Tuning intramolecular electron and energy transfer processes in novel conjugates of La<sub>2</sub>@C<sub>80</sub> and electron accepting subphthalocyanines

Tuning intramolecular electron and energy transfer processes in novel conjugates of La2@C80 and electron accepting subphthalocyanines

Tuning intramolecular electron and energy transfer processes in novel conjugates of La₂@C₈₀ and electron accepting subphthalocyanines