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The long sought solvated [MgCl](+) species in the Mg-dimer electrolytes was characterized by soft mass spectrometry. The presented study provides an insightful understanding on the electrolyte chemistry of rechargeable Mg batteries.

A fundamental study on the [(μ-Cl)3Mg2(THF)6]+ dimer electrolytes for rechargeable Mg batteries

A fundamental study on the [(μ-Cl)₃Mg₂(THF)₆]⁺ dimer electrolytes for rechargeable Mg batteries