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Palladium catalyzed allylic C-H functionalization was performed using exocyclic alkene substrates. Multi-component synthesis of stereodefined homoallylic alcohols could be performed using a reaction sequence involving allylic C-H borylation and allylation of aldehydes.

Allylic sp3 C–H borylation of alkenes via allyl-Pd intermediates: an efficient route to allylboronates

Allylic sp³ C–H borylation of alkenes via allyl-Pd intermediates: an efficient route to allylboronates