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A CO3(2-)-panelled [Gd(III)6Cu(II)3] cage conforming to a tridiminished icosahedron is synthesised by bubbling CO2 through a solution of Gd(III) and Cu(II) ions.

chemical communications

CO2 as a reaction ingredient for the construction of metal cages: a carbonate-panelled [Gd6Cu3] tridiminished icosahedron