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International audienceA bis(2-sulfanylethyl)amino PEG-based resin enabled the synthesis of large (~50 Aa) SEA or thioester peptides using Fmoc-SPPS. These peptide segments permitted the first total synthesis of a 97 amino acids long SUMO-1-SEA peptide thioester surrogate and of a functional and reversible SUMO-1 peptide conjugate

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A novel PEG-based solid support enables the synthesis of &gt;50 amino-acid peptide thioesters and the total synthesis of a functional SUMO-1 peptide conjugate