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Activation of C-C, C-N, and C-O bonds has in recent decades been recognized as a valuable strategic objective. While considerable progress has been achieved, many of the more challenging issues, e.g ., regioselective activation of specific C-X (C, O, N) bonds, chemoselective cleavage of C (sp3) -X bonds, enantioselective activation and even the successful application of solid catalysts in such transformations remain elusive. The research disclosed herein summarize recent advances in C-X bond cleavages, including regioselective processes, although the carbon is activated in the form of a cyano group.

Transformations of X (C, O, N)–CN bonds: cases of selective X (C, O, N)–C activation