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The first synthesis and structural elucidation of Ag(I) ternary complexes with 1,2-diazines and chelating heteroarenes have been described. Conserved modes of inter-cation Ag + ⋯ π and π ⋯ π stacking interactions result in near identical patterns of cation self-assembly in these ternary complexes.

Stacks and clips: uncanny similarities in the modes of self-assembly in ternary Ag(i) complexes with 1,2-diazines and chelating heteroarenes