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The biferrocene-based salt [Bifc]2[Ni(mnt)2]3 (Bifc = bis(isopropylthio)biferrocene; mnt = maleonitriledithiolate) contains a biferrocenium monocation and dication within the same crystal. The coexistence of Fe(3+) and mixed-valence Fe(2.5+), which resembles the valence state of magnetite, was confirmed by Mössbauer spectroscopy.

Biferrocenium salts with magnetite-like mixed-valence iron: coexistence of Fe3+ and Fe2.5+ in the crystal

Biferrocenium salts with magnetite-like mixed-valence iron: coexistence of Fe³⁺ and Fe^2.5+ in the crystal