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The reversible photolysis of aqueous [{FeIII(edta)}2O]4– leads to the evolution of oxygen and the formation of [FeII(edta)]2–; it is suggested that the photoreaction is induced by FeIII to FeIII charge-transfer excitation, which yields FeII and FeIVO in the primary photochemical step. \u

journal of the chemical society chemical communications

Photochemistry of the oxo-bridged diiron(<scp>III</scp>) core. Evolution of oxygen induced by Fe<sup>III</sup>to Fe<sup>III</sup>charge-transfer excitation of µ-oxobis[(ethylenediaminetetraacetato)ferrate(<scp>III</scp>)]

Photochemistry of the oxo-bridged diiron(III) core. Evolution of oxygen induced by FeIIIto FeIIIcharge-transfer excitation of µ-oxobis[(ethylenediaminetetraacetato)ferrate(III)]

Photochemistry of the oxo-bridged diiron(III) core. Evolution of oxygen induced by Fe^IIIto Fe^IIIcharge-transfer excitation of µ-oxobis[(ethylenediaminetetraacetato)ferrate(III)]