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Single crystal X-ray diffraction shows that Zr(iv) forms an octa-coordinated complex with 4 bidentate hydroxamates whose solution structures were investigated by utilizing density functional theory at the level of B3LYP/DGDZVP. Stability constants obtained by potentiometry were in accordance with the tendency observed when radiolabeling with (89)Zr.

chemical communications

Investigation of Zr(<scp>iv</scp>) and <sup>89</sup>Zr(<scp>iv</scp>) complexation with hydroxamates: progress towards designing a better chelator than desferrioxamine B for immuno-PET imaging

Investigation of Zr(iv) and 89Zr(iv) complexation with hydroxamates: progress towards designing a better chelator than desferrioxamine B for immuno-PET imaging

Investigation of Zr(iv) and ⁸⁹Zr(iv) complexation with hydroxamates: progress towards designing a better chelator than desferrioxamine B for immuno-PET imaging