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Dye-sensitized solar cells have been assembled using a sequential approach: a TiO(2) surface was functionalized with an anchoring ligand, followed by metallation with Zn(OAc)(2) or ZnCl(2), and subsequent capping with a chromophore functionalized 2,2':6',2''-terpyridine; the DSCs exhibit surprisingly good efficiencies confirming the effectiveness of the new strategy for zinc-based DSC fabrication.

The d10 route to dye-sensitized solar cells: step-wise assembly of zinc(ii) photosensitizers on TiO2 surfaces