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Tetraphenylporphyrin (TPP) rhodium chlorides coordinated by planar and twisted 4-phenylpyridine derivatives were synthesized. An STM image was taken by a 2-D phase separation technique and the conductance was evaluated. Difference in apparent height between these phenylpyridines reflects the conductance ratio of ligands.

chemical communications

Comparison of molecular conductance between planar and twisted 4-phenylpyridines by means of two-dimensional phase separation of tetraphenylporphyrin templates at a liquid–HOPG interface