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Chemoselective hydrogenation of water-insoluble aromatic nitro compounds can be achieved over Ni catalysts in a H2O-compressed CO2 system at 35-50℃ without using any environmentally harmful solvent. The effective CO2 pressure is much lower than the critical pressure of CO2. The hydrogenation of nitro group should be the rate-determining step

An effective medium of H2O and low-pressure CO2 for the selective hydrogenation of aromatic nitro compounds to anilines