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OH/R (R = H, Me, i-Bu) exchange was observed in reactions of [MesnacnacZn(μ-OH)](2) (1) with metal complexes L(n)MR, whereas DippnacnacAl(Me)OH reacts with MesnacnacZnH with elimination of H(2) and formation of the heterobimetallic Al-Zn-oxide complex MesnacnacZnOAl(Me)Dippnacnac 2.

X-Ray crystal structure of a heterobimetallic Al–Zn-oxide complex