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This work presents the synthesis and studies of a red-NIR luminescent liquid crystal compound based on an octahedral metallic cluster core orthogonally bounded to six non-mesogenic organic ligands. It evidences synergetic effects between the organic and inorganic parts of the hybrid, resulting in the generation of liquid crystal properties on cooling from the isotropic melt.

chemical communications

Liquid crystal properties resulting from synergetic effects between non-mesogenic organic molecules and a one nanometre sized octahedral transition metal cluster