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An encapsulated chloride in a thiophene-based cryptand is bridged by two in-in protons of tertiary amines with an N...Cl(-) distance of 3.048(3) A, similar to that observed in Park and Simmons' katapinand chloride complex.

Encapsulated chloride coordinating with two in–in protons of bridgehead amines in an octaprotonated azacryptand