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Thermal activation of terpyridine in the presence of an unsaturated Ir(III) fragment stabilized by a hydrotris(pyrazolyl) borate ligand gives rise to mononuclear complex and binuclear , in which the polypyridine behaves, respectively, as a mono- or a bi-dentate N-heterocyclic carbene.

chemical communications

Synthesis and structural characterization of a binuclear iridium complex with bridging, bidentate N-heterocyclic carbene coordination of 2,2′:6′,2″-terpyridine