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Reactions of the "salen" type Schiff bases H(2)L(1) and H(2)L(2) with Cd(OAc)(2).2H(2)O gave complexes with Cd(2) and Cd(3) cores and an extended 1-D framework architecture [H(2)L(1) = N,N'-(1,2-phenylenyl)-bis(5-bromo-2-hydroxy-3-methoxybenzaldimine; H(2)L(2) = N,N'-(propyl)-bis(5-bromo-2-hydroxy-3-methoxybenzaldimine)].

Multinuclear Cd2, Cd3 and 1-D framework structures of Cd(II) Schiff base complexes