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[Ph2BP(tBu)2]Cu-L complexes react with diazoalkanes to generate structurally unusual eta1-diazoalkane adducts, a terminal carbene, and an eta1-azine adduct.

chemical communications

Diazoalkanes react with a bis(phosphino)borate copper(i) source to generate [Ph2BPtBu2]Cu(η1-N2CR2), [Ph2BPtBu2]Cu(CPh2), and [Ph2BPtBu2]Cu–N(CPh2)(NCPh2)