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A novel supramolecular framework was obtained from the ligand H(2)BDOA (benzene-1,3-dioxyacetic acid) that exhibited an SrAl(2) topology with 1.7 x 1.7 nm channels formed by strong hydrogen bonds and demonstrated an interesting crystal-to-crystal transformation property.

An unprecedented nanoporous and fluorescent supramolecular framework with an SrAl2 topology controllably synthesized from a flexible ditopic acid