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Photoisomerization of encapsulated Z-enecarbamates within the hydrophobic chiral cavities of gamma-CD showed higher diastereoselectivities in the photoproducts than those obtained in solution. The selective encapsulation of the enecarbamates and the following isomerization process are both diastereoselectively controlled by gamma-CD.

chemical communications

Controlled diastereoselectivity at the alkene-geometry through selective encapsulation: E-Zphotoisomerization of oxazolidinone-functionalized enecarbamates within hydrophobic nano-cavities