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A microchip capillary electrophoretic reactor has been proposed and successfully demonstrated in the direct evaluation of the solvolytic dissociation rate constant of the complex of Ce3+ with a polyaminocarboxylic ligand, 8-amino-2-[(2-amino-5-methylphenoxyl)methyl]-6-methoxyquinoline-N,N,N',N'-tetraacetic acid.

A microchip capillary electrophoretic reactor: a new methodology for direct measurement of dissociation kinetics of metal complexes