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The in situ generated [Tp(Me2)Ir(C(6)H(5))(2)] fragment induces both aromatic and aliphatic C-H bond activation reactions, along with C-C bond formation, when heated with benzene and 1,2-dimethoxyethane.

chemical communications

Iridium solutes effect C–H bond activation and C–C bond forming reactions of C6H6–MeOCH2CH2OMe solvent mixtures