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The previously introduced three-phase electrode technique was used to determine the Gibbs energies of\udtransfer of ClO3\ud, BrO3\ud, IO3\ud, IO4\ud, OCN, SeCN, CN, N3\ud, halogen substituted acetate anions\udZ3nCHnCOO (Z ¼ F,Cl,Br,I), and cycloalkyl carboxylate anions ((CH2)nCOO, n ¼ 3,. . .,7) at the\udwater|nitrobenzene interface. Whereas the data for the small inorganic ions can easily be understood\udin terms of ion-dipole interactions, the data of the organic ions need consideration of charge\uddelocalisation and its effect on the enthalpy and entropy of solvation

physical chemistry chemical physics

Standard Gibbs energies of transfer of halogenate and pseudohalogenate ions, halogen substituted acetates, and cycloalkyl carboxylate anions at the water|nitrobenzene interface