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The existence of a strong correlation between ligand architecture and metal ion binding selectivity is demonstrated through large differences in the separation efficiencies found in the selective extraction of Am3+ from an acidic mixture of Am3+ and Eu3+ for three new tetrapodal hexadentate ligands containing four 2-pyrazinylmethyl groups attached to three different diamino spacers.

chemical communications

The important effect of ligand architecture on the selectivity of metal ion recognition in An(<scp>iii</scp>)/Ln(<scp>iii</scp>) separation with N-donor extractants

The important effect of ligand architecture on the selectivity of metal ion recognition in An(iii)/Ln(iii) separation with N-donor extractants