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A circular dichroic (CD) excition chirality method based on host-guest chiral recognition has been developed to determine the absolute configuration of carboxylic acids with an alpha-stereogenic center; an amide C = O--&gt;Zn coordination, identified by infrared spectroscopy and computations, is involved in this complexation.

chemical communications

Configurational assignment of α-chiral carboxylic acids by complexation to dimeric Zn–porphyrin: host–guest structure, chiral recognition and circular dichroismElectronic supplementary information (ESI) available: spectroscopic data for compounds 1–7/2 and 3–7/2 to 6–7/2; UV-Vis spectra and binding curves for titration of 2 with 1–8; Job plot for 1–8/2; computational and experimental sections. See http://www.rsc.org/suppdata/cc/b2/b204554k/