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We outline a conceptually simple and general route to bowl-shaped benzocorannulenes based on readily assembled PAHs which on flash vacuum pyrolysis result in the sequential formation of a five- and six-membered ring; following this approach, syntheses of mono-, di- and tri-benzocorannulenes have been achieved.

Bucky-bowls. A general approach to benzocorannulenes: synthesis of mono-, di- and tri-benzocorannulenes