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The phosphor-converted warm W-LED have being rapidly developed due to the stringent requirements of general illumination. Here, we utilized a strategy to synergistically enhance the red region and emission intensity of novel Eu-activated yellow-emitting LaSiO 2 N phosphors. This was realized by predicting optimum crystal structure, and governing the concentration of doping ions as well as preparation temperature. By using these straight-forward methods, we were able to vary the valence to enhance the red region and improve the quantum efficiency of LaSiO 2 N phosphor. The warm W-LED lamp fabricated with this red region enhanced LaSiO 2 N:Eu phosphor exhibited high CRI (Ra = 86), suitable CCT (5783 K) and CIE chromaticity (0.33, 0.36), indicating this synergistically enhanced strategy could be used for design of yellow-emitting phosphor materials to obtain warm W-LEDs.

Design of a Yellow-Emitting Phosphor with Enhanced Red Emission via Valence State-control for Warm White LEDs Application