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In order to make fast-charging batteries a reality for electric vehicles, durable, more energy dense and high-current density resistant anodes need to be developed. With such purpose, a low lithiation potential of 0.2 V vs. Li/Li +  for MoO 3  nanoplatelet arrays is reported here for anodes in a lithium ion battery. The composite material here presented affords elevated charge capacity while at the same time withstands rapid cycling for longer periods of time. Li 2 MoO 4  and Li 1.333 Mo 0.666 O 2  were identified as the products of lithiation of pristine MoO 3  nanoplatelets and silicon-decorated MoO 3 , respectively, accounting for lower than previously reported lithiation potentials. MoO 3  nanoplatelet arrays were deposited using hot-wire chemical vapor deposition. Due to excellent voltage compatibility, composite lithium ion battery anodes comprising molybdenum oxide nanoplatelets decorated with silicon nanoparticles (0.3% by wt.) were prepared using an ultrasonic spray. Silicon decorated MoO 3  nanoplatelets exhibited enhanced capacity of 1037 mAh g −1  with exceptional cyclablity when charged/discharged at high current densities of 10 A g −1 .

High rate and durable, binder free anode based on silicon loaded MoO3 nanoplatelets