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Crystal structures of silane have been extensively investigated using  ab initio  evolutionary simulation methods at high pressures. Two metallic structures with  P 2 1 / c  and  C 2/ m  symmetries are found stable above 383 GPa. The superconductivities of metallic phases are fully explored under BCS theory, including the reported  C 2/ c  one. Perturbative linear-response calculations for  C 2/ m  silane at 610 GPa reveal a high superconducting critical temperature that beyond the order of 10 2  K.

High-temperature Superconductivity in compressed Solid Silane