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We demonstrate thermo-electrochemical (TEC) conversion using a biocompatible redox couple of lactic acid and pyruvic acid on earth-abundant TiO 2 . The TEC cell exhibited a positive Seebeck coefficient of 1.40 mV K −1 . DFT calculations figured out that the adsorption of intermediate species and protons on TiO 2  controls both the redox reaction and current polarity.

Inversely polarized thermo-electrochemical power generation via the reaction of an organic redox couple on a TiO2/Ti mesh electrode