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Multiple modes of atomization in electrosprays are affected by viscosity, surface tension and electrical conductivity of the semiconductor nanosuspensions. While the effect of gravity is dominant in the dripping mode, the electric field degenerates the electrospray mechanism into a microdripping mode that can potentially allow the deposition of semiconductor nanodots on a substrate. Drop size and frequency of droplet formation are obtained as functions of non-dimensional parameters, which agree well with experimental data. The analysis shows that it is possible to produce the desired size and frequency of ejection of monodisperse droplets by manipulating the electrode voltage for any nanosuspension.

Non-dimensional groups for electrospray modes of highly conductive and viscous nanoparticle suspensions