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One of the major challenges of near-equiatomic NiTi shape memory alloys is their limitation for high-temperature applications. To overcome this barrier, researchers have tried to enhance the transformation temperatures by addition of alloying elements or even by introducing the concept of high-entropy alloys (HEAs). In this study, the CuNiHfTiZr HEAs were developed for high-temperature shape memory effect. Based on their solubility and electron configurations, the alloying elements are divided into two groups, (CuNi) 50  and (HfTiZr) 50 . The content of Cu in (CuNi) 50  is modulated to investigate the influences of Cu on martensitic transformation of the HEAs by studying structural evolution and transformation behavior. The results of x-ray diffraction and thermal expansion tests revealed that Cu 15 Ni 35 Hf 16.67 Ti 16.67 Zr 16.67  possesses high transformation temperature, narrow hysteresis temperature loops, and good dimensional stability within this HEA system.

High-temperature martensitic transformation of CuNiHfTiZr high- entropy alloys