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Graphite is used commercially as the active material in lithium ion batteries, frequently as part of a graphite/SiO x  composite. Graphite is used in conjunction with SiO x  to overcome the limited energy density of graphite, and to lessen the adverse effects of volume expansion of Si. However, electrodes based on graphite/SiO x  composites can be made with only 3–5 wt % SiO x  because of the increased failure of electrodes with higher SiO x  contents. Here, we developed a new polymer binder, by combining dopamine-grafted heparin with the commercial binder carboxymethyl cellulose (CMC)/styrene butadiene rubber (SBR), in order to more effectively hold the SiO x  particles together and prevent disintegration of the electrode during charging and discharging. The crosslinking using acid-base interactions between heparin and CMC and the ion-conducting sulfonate group in heparin, together with the strong adhesion properties of dopamine, yielded better physical properties for the dopamine-heparin-containing CMC/SBR-based electrodes than for the commercial CMC/SBR-based electrodes, and hence yielded excellent cell performance with a retention of 73.5% of the original capacity, a Coulombic efficiency of 99.7% at 150 cycles, and a high capacity of 200 mAh g −1  even at 20 C. Furthermore, a full cell test using the proposed electrode material showed stable cell performance with 89% retention at the 150 th  cycle.

scientific reports

Dopamine-grafted heparin as an additive to the commercialized carboxymethyl cellulose/styrene-butadiene rubber binder for practical use of SiOx/graphite composite anode