English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Tools annual

Global: Zendy Free Plan

Global: Zendy Tools monthly

Global: Zendy Plus monthly

Near-infrared light-emitting electrochemical cell (NIR-LEEC) has emerged as a new and promising lighting sourcewhich could serve as low-cost alternatives in NIR light-emitting sources which are typically expensive. LECs were also shown advantages such as light weight, simplicity and low operation voltages. However, only a few examples of NIR-LEEC are reported in which external quantum efficiency(EQE) of devices limited to 0.1%. Here, we report, efficient NIR-LEEC based of two novel binuclear ruthenium phenanthroimidzole complex which differ by employing the type of ancillary ligand including 2, 2′bipyridine (bpy) (B1) and 4, 4′ dimethyl bpy (B2) that realize maximum EQE of 0.14 and 0.68% and extremely long excited state lifetimes of 220 and 374 ns for thin film were estimated, respectively, indicating that influences of substitution on ancillary ligand. Moreover, this substitution dramatically influences other electroluminescence metrics including decreasing turn on voltage from 4.5 to 3.1 V, increasing maximum luminance (L max ) from 193to 742 cd.m −2  and increasing lifetime from 539 to 1104 second, which are the best value among the binuclear ruthenium polypyridyl complexes to date.

scientific reports

Efficient near infrared light emitting electrochemical cell (NIR-LEEC) based on new binuclear ruthenium phenanthroimidazole exhibiting desired charge carrier dynamics