English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Tools annual

Global: Zendy Free Plan

Global: Zendy Tools monthly

Global: Zendy Plus monthly

The isotropic and anisotropic parts Raman spectra of γ-Caprolactone in the binary mixture at different concentrations have been measured. The non-coincidence effect (NCE) of γ-Caprolactone was determined in carbon tetrachloride solution and DMSO solution. The NCE of the ν 11 (C=O) stretching mode in the γ-Caprolactone/DMSO mixtures exhibits a linear plot, in contrast to that in the γ-Caprolactone/CCl 4  mixtures, which shows an upward (convex) curvature. The reduction and enhancement of the dimer structure (short-range orientational order) of γ-Caprolactone in the γ-Caprolactone/DMSO and γ-Caprolactone/CCl 4  mixtures respectively may play a major role in shifting of peak frequencies, thus the geometries of monomer and dimer of γ-Caprolactone were calculated at the B3LYP-D3/6–311 G (d,p) level of theory. We proposed aggregated model to explain the γ-Caprolactone C=O vibration NCE phenomenon and its concentration effect and found it largely consistent with our experimental findings. Solvent dependent experiment show the value of NCE declined with the increase of the solvent dielectric constant under the same condition which is consistent with the Logan’s theory.

Local order and vibrational coupling of the C=O Stretching Mode of γ-Caprolactone in liquid binary mixtures