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Doped clusters in the gas phase provide nanoconfined model systems for thestudy of system-bath interactions. To gain insight into interaction mechanismsbetween chromophores and their environment, the ensemble inhomogeneity has tobe lifted and the homogeneous line profile must be accessed. However, suchmeasurements are very challenging at the low particle densities and low signallevels in cluster beam experiments. Here, we dope cryogenic rare-gas clusterswith phthalocyanine molecules and apply action-detected two-dimensionalelectronic spectroscopy to gain insight into the local molecule-clusterenvironment for solid and superfluid cluster species. The high-resolutionhomogeneous linewidth analysis provides a benchmark for the theoreticalmodelling of binding configurations and shows a promising route forhigh-resolution molecular two-dimensional spectroscopy.

High-resolution two-dimensional electronic spectroscopy reveals homogeneous line profiles in isolated nanoparticles