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The use of graphene in a form of discontinuous flakes in polymer compositeslimits the full exploitation of the unique properties of graphene, thusrequiring high filler loadings for achieving - for example - satisfactoryelectrical and mechanical properties. Herein centimetre-scale CVDgraphene/polymer nanolaminates have been produced by using an iterative'lift-off/float-on' process and have been found to outperform, for the samegraphene content, state-of-the-art flake-based graphene polymer composites interms of mechanical reinforcement and electrical properties. Most importantlythese thin laminate materials show a high electromagnetic interference (EMI)shielding effectiveness, reaching 60 dB for a small thickness of 33 micron, andan absolute EMI shielding effectiveness close to 3* 10 ^5 dB cm ^2 g^-1 whichis amongst the highest values for synthetic, non-metallic materials produced todate.

Effective EMI shielding behaviour of thin graphene/PMMA nanolaminates in the THz range