English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Plus monthly

Global: Zendy Tools annual

Global: Zendy Tools monthly

Global: Zendy Free Plan

PMe(3) adds selectively to the central carbon of the η(3)- propargyl complex [C(5)Me(5)(CO)(2)Re(η(3)-CH(2)C≡CCMe(3))][BF(4)] (1-t-Bu) to form the metallacyclobutene [C(5)Me(5)(CO)(2)Re(CH(2)C(PMe(3))=CCMe(3))][BF(4)] (7). The rate of rearrangement of the metallacyclobutene 7 to η(2)-alkyne complex [C(5)Me(5)(CO)(2)Re(η(2)-Me(3)PCH(2)C≡CCMe(3))][BF(4)] (8) is is independent of phosphine concentration, consistent with a dissociative mechanism proceeding via η(3)-propargyl complex 1-t-Bu. The rate of this rearrangement is 480 times slower than the rate of exchange of PMe(3) with the labeled metallacyclobutene 7-d(9). This rate ratio provides an indirect measurement of the regioselectivity for addition of PMe(3) to the central carbon of η(3)-propargyl complex 1-t-Bu to give 7 compared to addition to a terminal carbon to give 8. The addition of PPh(3) to 1-t-Bu gives the metallacyclobutene [C(5)Me(5)(CO)(2)Re(CH(2)C(PPh(3))=CCMe(3))][BF(4)] (11). Low temperature (1)H NMR spectra provide evidence for an equilibrium between metallacyclobutene 11 and η(3)-propargyl complex 1-t-Bu (K(eq) ≈ 44 M(-1) at -46 °C and ΔG° (0 °C) = -1.2 ± 0.2 kcal mol(-1)).

organometallics

Quantitative Determination of the Regioselectivity of Nucleophilic Addition to η<sup>3</sup>-Propargyl Rhenium Complexes and Direct Observation of an Equilibrium between η<sup>3</sup>-Propargyl Rhenium Complexes and Rhenacyclobutenes

Quantitative Determination of the Regioselectivity of Nucleophilic Addition to η3-Propargyl Rhenium Complexes and Direct Observation of an Equilibrium between η3-Propargyl Rhenium Complexes and Rhenacyclobutenes

Quantitative Determination of the Regioselectivity of Nucleophilic Addition to η³-Propargyl Rhenium Complexes and Direct Observation of an Equilibrium between η³-Propargyl Rhenium Complexes and Rhenacyclobutenes