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A kinetic isotope effect (kD/kH) of 7.4 has been found for the reaction of chlorosilylene with trimethylsilane (Me3SiD vs Me3SiH). Such a value can be accounted for by theoretical modeling, but only if an internal rearrangement of the initially formed complex is included in the mechanism. This provides the first concrete evidence for such complexes.

organometallics

Dramatic Isotope Effect in the Reaction of ClSiH with Trimethylsilane-1-<i>d</i>: Experimental Evidence for Intermediate Complexes in Silylene Si–H(D) Insertion Reactions

Dramatic Isotope Effect in the Reaction of ClSiH with Trimethylsilane-1-d: Experimental Evidence for Intermediate Complexes in Silylene Si–H(D) Insertion Reactions