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O-Acetyl oximes serve as effective directing groups for Pd-catalyzed sp(2) and sp(3) C-H functionalization reactions. The C-H functionalization products can be subsequently transformed into ortho- or beta-functionalized ketones, alcohols, amines, and heterocycles.

O-Acetyl Oximes as Transformable Directing Groups for Pd-Catalyzed C−H Bond Functionalization