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Using empirical scheme, atomic structure of a new exotic class of siliconnanoclusters was elaborated upon the central icosahedral core (Si-IC) andpentagonal petals (Si-PP) growing from Si-IC vertexes. It was shown thatSi-IC/Si-PP interface formation is energetically preferable. Some experimentalobservations of silicon nanostructures can be explained by presence of theproposed objects. The Extended Huckel Theory electronic structure calculationsdemonstrate an ability of the proposed objects to act as nanoscale tunneljunctions.

Multiterminal Nanowire Junctions of Silicon: A Theoretical Prediction of Atomic Structure and Electronic Properties