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We show by combining small-angle X-ray scattering (SAXS) andcryo-transmission electron microscopy (cryo-TEM) that anionic silicananoparticles (SiNPs) assemble into well-defined 1D cluster when mixed with adilute solution of semiflexible chitosan polycation. The nanorods are stable inexcess of SiNPs and composed of 10 SiNPs well-ordered into straight singlestrands with length Lrod \approx 184.0 nm and radius Rrod = 9.2 nm = RSiNPs. Wepoint out that the ratio between the chitosan persistence length and the SiNPradius, which is here equal to 1, can be the determining condition to obtainsuch original objects.

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Nanorods of Well-Defined Length and Monodisperse Cross-Section Obtained  from Electrostatic Complexation of Nanoparticles with a Semiflexible  Biopolymer